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Friday, November 24, 2017

Most Number Of...

What if, we are to use vp instead of vrms in the discussions of perovskites solar cells and superconductors,

Tvp=v2boommolarmass10328.3144

Tvp=32Tboom

In the case of MgO3Ti with, Zm=22+12+83=58 a density of  3.36gcm3 and molar mass of 120.17gmol1. Its Tvp is,

vboom=3.4354336058=199.01

Tvp=199.012120.1710328.3144=286.21K or 13.06oC

For ZnTiO3,

Tvp=32354.41=531.62K  or 258.46oC

For TiCaO3,

350.91K<Tvp<402.0K  or  77.76oC<Tvp<128.85oC

For FeTiO3,

458.79K<Tvp<476.50K  or  185.64oC<Tvp<203.36oC

For MnTiO3,

Tvp=437.01K  or  163.83oC

It seems that only by reducing the density of high value Tvp perozskites can Tvp at room temperature be achieved.  For example a 82.60% MnTiO3 has a Tvp of

Tvp=0.82602437.01=298.16K  or  25.01oC

The rest of the 100%, 17.40% can be with Fe, FeTiO3, as long as they can form into the same crystal structure.

Reducing density can only reduce Tvp; Tvp cannot be increased this way.  Density can only be reduced given a crystalline structure.

It is likely that vp provides the most number of freed particles that will act as charge carriers.  Super-superconductor...The difference between vp and vrms is,

vp=23vrms=0.667vrms

vp should be used instead of vrms; we should set vp=2RTnMm=vboomvrms such that T=Tboom.

And it rains again...