Monday, November 13, 2017

More Ethanol

More extensive data for ethanol \(CH_3CH_2OH\) is presented below,

Temp (K)Densityx10^3 (kg/m3) v boom (m/s)    T boom (K)     n
378.1570693.28416.0723.53
373.1571193.94516.3022.89
368.1571794.73816.5822.21
363.1572295.39816.8121.60
358.1572896.19117.0920.96
353.1573396.85217.3220.38
348.1573897.51317.5619.82
343.1574398.17317.8019.28
338.1574898.83418.0418.74
333.1575399.49418.2818.22
328.15758100.15518.5317.71
323.15763100.81618.7717.21
318.15768101.47619.0216.73
313.15772102.00519.2216.30
308.15777102.66619.4715.83
303.15781103.19419.6715.41
298.15786103.85519.9214.97
293.15790104.38320.1214.57
288.15795105.04420.3814.14
283.15799105.57220.5913.76
278.15803106.10120.7913.38
273.15808106.76221.0512.98
268.15812107.29021.2612.61
263.15816107.81921.4712.26
258.15820108.34721.6811.91
253.15824108.87621.8911.56
248.15828109.40422.1111.23
243.15832109.93322.3210.89
238.15836110.46122.5410.57
233.15840110.99022.7510.25
228.15844111.51822.979.93
223.15848112.04723.199.62
218.15851112.44323.359.34
213.15855112.97223.579.04
208.15859113.50023.798.75
203.15863114.02924.018.46
198.15866114.42524.188.19
193.15870114.95424.417.91
188.15874115.48224.637.64
183.15877115.87924.807.38
178.15881116.40725.037.12
173.15884116.80425.206.87
168.15888117.33225.436.61
163.15891117.72925.606.37

\(n\) increases as temperature increases throughout the range of temperature presented, and beyond the boiling point at \(351.39\,K\).

\(n\) increasing with temperature is consistent with increasing thermal energy \(\cfrac{3}{2}kT\) with temperature, but clustered particles seem intuitively less likely to increase in size with temperature.  Increase in collisions is likely to break clustered particles apart.  BUT density is decreasing, that means there is more space between particles as temperature increases.  Maybe collisions decreases with lowered density and clustering increases with temperature as density drops, with more space between clustered particles.

Taken to higher temperature, before disintegration, clustering could result in large macro-molecules in high velocity.  Is that possible?  The least value of \(n\) is one, \(n\ge1\)

What is the nature of such clustering?  Temperature particles acting like waves and coalesce?  Is clustering electrostatic as the particles break from the lattice are positively charged.

Is \(n\) even valid?