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Friday, November 10, 2017

Coal Fire Again

The problem is Lignite (a form of coal) has a density of only 801kgm3 which would mean,

vboomlignite=3.43548016=458.63ms1

and

Tp=458.63212.010710328.3144=151.93K

Lignite will spontaneously ignite at 151.93273.15=121.22oC!  What happened?  Apparently, lignite low density value is due to bulk (air space) and is not structural.  The quoted density value is bulk density.

In the case of Anthracite, another form of coal, with a density value of 1506kgm3,

vboomanthracite=3.435415066=862.29ms1

and

T862=862.29212.010710328.3144=537.04K

It will ignite at 263.90oC

And bituminous coal of a density 1346kgm3,

vboombituminous=3.435413466=770.67ms1

and

T770=770.67212.010710328.3144=428.98K

It will ignite at 155.83oC.

And another quoted value of density for coal at 1400kgm3

vboombrown=3.435414006=801.59ms1

and

T770=801.59212.010710328.3144=464.10K

It ignites at 190.95oC

Crystalline (structural) density should be used and not bulk density in the calculations for vboom and Tvboom.

Do we need to differentiate vrms and vp and so, Tvboom and Tboomp?

Apparently you need to have most of the particles at vboom (vp=vboom) to ignite the matter, and afterwards the matter settles to a temperature where the particles has a vrms at vboom.  ie.  (vrms=vboom).  In the former case, we are concerned with velocities at which most particles collide and in the latter, we are concerned with the mean of velocities squared of the particles as indicative of its energy content; the measured temperature according to Kinetic Theory for Ideal gases.

Speculative...  still go put out the coal fire.