Tuesday, December 12, 2017

Pressure, Energy Per Unit Vol

From ideal gas,  This should not be ideal gas please refer to "Conceptual Mishap Clustering" dated 13 Dec 2017,

\(T=\cfrac{1}{n}.\cfrac{PV}{R}\)

\(T=\cfrac{V}{n}.\cfrac{P}{R}=\cfrac{1}{\rho_n}.\cfrac{P}{R}\)

so,

\(P=\rho_nRT\)

From the post "Going Back To Durian Constantly" dated 09 Nov 2017,

\(T=\cfrac{(2c)^3}{3}*\cfrac{1}{2}m_av^2_{rms}\)

so,

\(P=\rho_nR.\cfrac{(2c)^3}{3}*\cfrac{1}{2}m_av^2_{rms}\)

\(P=\cfrac{1}{3}\rho_nR.{(2c)^3}*\cfrac{1}{2}m_av^2_{rms}\)

If \(R=2*\cfrac{4}{3}\pi\)

\(P=\cfrac{2}{3}\rho_n*\cfrac{4}{3}\pi{(2c)^3}*\cfrac{1}{2}m_av^2_{rms}\) --- (*)

where \(\cfrac{1}{3}\) accounts for one of the three space dimensions.  The term,

\(\rho_n*\cfrac{4}{3}\pi{(2c)^3}*\cfrac{1}{2}m_av^2_{rms}\)

the total kinetic energy in a volume of radius \(2c\).  It is likely that the factor \(2\) accounts for both positive and negative directions.  The expression however is not dimensional-ly consistent.

Consider, \(V=\cfrac{4}{3}\pi x^3\),

\(\cfrac{dV}{dx}=3*\cfrac{4}{3}\pi x^2\)

\(\cfrac{d^2V}{dx^2}=2*3*\cfrac{4}{3}\pi x\)

\(\cfrac{d^3V}{dx^3}=1*2*3*\cfrac{4}{3}\pi=3R\)

in which case \(R\) is the change of a volume in all 3 space dimensions and has unit "\(vol\,m^{-3}\)" scaled by \(\cfrac{1}{3}\) to consider only one direction of \(x\).

This might account for the unit of the expression (*).  Then,

\(P=\cfrac{2}{3}\rho_n*\cfrac{4}{3}\pi{(2c)^3}*\cfrac{1}{2}m_av^2_{rms}\)

is energy per unit volume \(r=2c\), or force per unit area as energy per meter is force.

\(\cfrac{E}{m^3}=\cfrac{F}{m^2}\)

\(\because\)

\(\cfrac{E}{x}=F\)

What is the factor \(\cfrac{2}{3}\) for?