Vmin=12miq(3.4354∗densityZ)2
mi is the mass of one particle.
Vmin=12MqNA(3.4354∗densityZ)2
M is molar mass and NA, Avogadro's number.
Atomic No. | Name | Symbol | Mass(g/mol) | Density(g/L) | v_boom(m/s) | Vmin(V) |
2 | Helium | He | 4.002602 | 0.1785 | 0.3066 | 1.9501E-09 |
10 | Neon | Ne | 20.1797 | 0.8999 | 0.3092 | 9.9952E-09 |
18 | Argon | Ar | 39.948 | 1.7837 | 0.3404 | 2.3993E-08 |
36 | Krypton | Kr | 83.798 | 3.733 | 0.3562 | 5.5110E-08 |
54 | Xenon | Xe | 131.293 | 5.887 | 0.3745 | 9.5440E-08 |
86 | Radon | Rn | 222 | 9.73 | 0.3887 | 1.7381E-07 |
This set of data assumes that the noble gas atom with a charge of q is accelerated under the voltage Vmin across a gap of d=1m to achieve the speed vboom.
This set of values for Vmin is too low, a typical discharge voltage value for Argon, for a gap of 12μm is 137V.
If we take the per atom view, instead of per particle view above,
Vmin=12miq(3.4354∗density∗Z)2
Vmin=12MqNA(3.4354∗density∗Z)2
where we have taken that an atom with Z number of particles (of one type), with a charge of q, is accelerated under Vmin for a meter (d=1m) to achieve vboom speed.
Atomic No. | Name | Symbol | Mass gmol−1 | Density gL−1 | v_boom ms−1 | Vmin V | Vmin ÷12μm |
1 | Hydrogen | H2 | 2.016 | 0.0899 | 0.1544 | 3.9844E-09 | 3.32E-04 |
2 | Helium | He | 4.002602 | 0.1785 | 0.3066 | 3.120E-08 | 2.60E-03 |
10 | Neon | Ne | 20.1797 | 0.8999 | 0.3092 | 9.995E-05 | 8.33E+00 |
18 | Argon | Ar | 39.948 | 1.661 | 0.3170 | 2.184E-03 | 1.82E+02 |
36 | Krypton | Kr | 83.798 | 3.733 | 0.3562 | 9.256E-02 | 7.71E+03 |
54 | Xenon | Xe | 131.293 | 5.887 | 0.3745 | 8.115E-01 | 6.76E+04 |
86 | Radon | Rn | 222 | 9.73 | 0.3887 | 9.507E+00 | 7.92E+05 |
The last column is,
V=Vmind
d=12μm
to obtain the value of the minimum discharge voltage V for a gap of 12μm. The minimum discharge voltage for a gap distance of 12μm for Argon is 182V. This is higher than the quoted value of 137V. (A higher voltage is needed for a gap smaller than one meter, because the particle must reach vboom before reaching the opposite electrode.)
Notice that to accelerate Helium He to the correct vboom speed within a similar gap, the applied voltage is in the mini-voltage (mV) range. And for Neon Ne, a few volts. Hydrogen gas, interestingly is discharged at ≈0.33mV, which is at the cellular voltage level.
Good day!
Note: Vmin=0.5*(3.4354*density/Z)^2*M/(6.0221*10^23*1.6021*10^(-19)*10^3) for the first table.
Vmin=0.5*(3.4354*density*Z)^2*M/(6.0221*10^23*1.6021*10^(-19)*10^3) for the second table.
Note: Hydrogen gas was added to the last table on 29 Dec 2017.