In the per particle view, a given density is shared by Z particles.
In the per atom view, a given density has Z particles.
In the per particle view, the whole atom is moving (with a given KE) and carries with it Z particles.
In the per atom view, the atom is bombarded with photons, each atom has Z particles that can interact with the photons.
In,
Einputatom=Ephoton=...density∗Z...
photons interacts with an atom with Z particles. More energy is needed to interact with an atom, where Z particle coalesce into one as a quasi-nucleus. The atom is stationary, photons move and collide with it.
In,
Einputparticle=Eparticle=...densityZ...
particles interacts with particles. Less energy is needed to interact at individual particle level compared to the interaction with a quasi-nucleus. Relatively, the atom is moving in space with Z number of particles. A gas.
Maybe in a solid, we should have taken the per atom perspective too. In this case free particles move within the confines of the solid.
Good morning!