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Thursday, April 7, 2016

And She Does The Split!

More poison but where is triple bond?



Carbon monoxide, none of the five pairs of orbits n=5, stands out to be counted as part of triple bond.

Unfortunately,


This is not valid for carbon dioxide, CO2.  As the molecule is linear, but in that case, the center C does not have a valid Quantum Number.  There is however another solution,

Carbon has an n=2. Two Oxygen atoms are bonded to the Carbon orbits that are perpendicular to each other.  But being free to rotate, one of the orbits rotates by 90o, still rotating in a plane perpendicular to the other orbit pair and spreads the two oxygen atoms furthest apart.  The molecule is then linear.

Hew!