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Thursday, September 18, 2014

Theoretically Infinite

Consider again,

re=me2Aof(lnT){114Aof(lnT)merec}

dredT=ddT{me2Aof(lnT)}.{114Aof(lnT)merec}+me2Aof(lnT).ddT{114Aof(lnT)merec}

The gradient just before the kink at  re=2rec is,

dredT=ddT{me2Aof(lnT)}

dredT=me2AoddT{1f(lnT)}

dredT=me2Aoddln(T){1f(lnT)}dln(T)dT

dredT=me2Ao1f(lnT)2.f(ln(T)).1T

dredT=me2Ao1T1f(lnT)2.f(ln(T))

From the post "Band Gap? Just A Kink",

Aof(lnT)=me4rec

f(lnT)2=me216A2or2ec

So,

dredT=me2Ao1T.16A2or2ecme2f(ln(T))

dredT=8Aor2ecme1T.f(ln(T))

dredT=8Aor2ecme1T.df(ln(T))dTdTdln(T)

dredT=8Aor2ecme.df(ln(T))dT

And for the case of a single electron orbiting about a single positive charge,  rec  the orbiting radius without considering drag is,

rec=q24πεomev2

and v2=2c2

dredT=8Aome.q464π2ε2om2ec4.df(ln(T))dT

dredT=Aoq48π2ε2om3ec4.df(ln(T))dT

For a nucleus of atomic number  n,

dredT=Aon2q48π2ε2om3ec4.df(ln(T))dT 

The gradient just after the kink is, theoretically,

dredT

From the post "Gap, Gap, Gap and Quack",

d(re)dt=d(re)dTdTdx

where  dTdx  is the temperature profile around the nucleus.  Thus, the velocity before the kink at  re=2rec,

d(re)dt=8Aor2ecme.df(ln(T))dTdTdx

the negative sign indicates that the electron is moving towards the nucleus, decreasing  re.  In general for a nucleus of   n  positive charge.

d(re)dt=Aon2q48π2ε2om3ec4.df(ln(T))dTdTdx

And the velocity just after the kink is,

dredt

theoretically.