ΔE1→2=0.2063hfψc
and so we have,
aψnew=0.2063aψ
thus assuming that the first spectra line is of double intensity, ie from the pair (n2=2,n1=1),
aψ=0.2063∗19.34=3.99nm
aψ=0.2063∗16.32=3.37nm
aψ=0.2063∗15.48=3.19nm
aψ=0.2063∗14.77=3.05nm
If, the first spectra line is the result of (nlarge,1),
aψ=0.762∗19.34=14.74nm
aψ=0.762∗16.32=12.44nm
aψ=0.762∗15.48=11.80nm
aψ=0.762∗14.77=11.25nm
Which is just a bunch of numbers. However, both cases point to the fact that the calculated fψ from Planck's relation, ΔE=h.fψ, is not the frequency fψc of ψ, to resonate the particle with. fψc is defined as,
fψc=cλψc=c2πaψc
where there is one wavelength m=1 around the circular path of ψ with radius aψc .
Depending on which spectra line is used to derive fψ, a factor of 0.2063 or 0.762 applies. In the case where both the double intensity emission spectra line and the first absorption spectra line are used, with the appropriate factor, there can be only one value for fψc.
Where do all these lead us?
ΔE2→1=h.fψc(3√n2−3√n13√n1n2)
The murder of Rydberg constant?
1λ2→1=RH(1n21−1n22)
Comparing the two expressions,
RH=12πaψc
which is a constant given aψc. Maybe...