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Thursday, October 13, 2016

Looking for Murder

From the previous post "" dated 13 Oct 2016,

ΔE12=0.2063hfψc

and so we have,

aψnew=0.2063aψ

thus assuming that the first spectra line is of double intensity, ie from the pair (n2=2,n1=1),

aψ=0.206319.34=3.99nm

aψ=0.206316.32=3.37nm

aψ=0.206315.48=3.19nm

aψ=0.206314.77=3.05nm

If, the first spectra line is the result of (nlarge,1),

aψ=0.76219.34=14.74nm

aψ=0.76216.32=12.44nm

aψ=0.76215.48=11.80nm

aψ=0.76214.77=11.25nm

Which is just a bunch of numbers.  However, both cases point to the fact that the calculated fψ from Planck's relation, ΔE=h.fψ, is not the frequency fψc of ψ, to resonate the particle with.  fψc is defined as,

fψc=cλψc=c2πaψc

where there is one wavelength m=1 around the circular path of ψ with radius aψc .

Depending on which spectra line is used to derive fψ, a factor of 0.2063 or 0.762 applies.  In the case where both the double intensity emission spectra line and the first absorption spectra line are used, with the appropriate factor, there can be only one value for fψc.

Where do all these lead us?

ΔE21=h.fψc(3n23n13n1n2)

The murder of Rydberg constant?

1λ21=RH(1n211n22)

Comparing the two expressions,

RH=12πaψc

which is a constant given aψc.  Maybe...