From the previous post "Like Wave, Like Particle, Not Attracted to Electrons", the energy in required in moving from r at ∞ to reo is
PEe=mec2limr→∞{ln(rreo)+C(reo−r)}
Energy required in moving from ∞ to ref is
PEe=mec2limr→∞{ln(rref)+C(ref−r)}
So, the energy required in moving the electron from from reo to ref is
Es=PEe(ref)−PEe(reo)
Es=mec2limr→∞{ln(rref)−ln(rreo)+C(ref−r)−C(reo−r)}
Es=mec2{ln(reoref)+C(ref−reo)}
which is the same expression as Es as before.
From previous calculation of atomic radius we find that, the centripetal force is of the form,
mec2reo=q24πεor2eo.(4−383).√32√232
and
mec2reo=q24πεor2eo(3−√33)
In general,
mec2reo=q24πεor2eo.A
where A is a numerical constant dependent on the configuration of the electrons around the positive charge. Using this expression to bring a charge from infinity to its final configuration position along the line joining it and the positive center.
PE=−A∫reor→∞−q24πεor2dr
PE=−q2A4πεo{1r}|reor→∞
PE=−q2A4πεo1reo
The negative sign indicates that this potential is lower than that at ∞ which is zero. Numerically, the energy stored when the electron is pushed to a lower orbit, (photon and electron repel) is equal to this PE when the electron is ejected (ie the atom is ionized) after the photon has passed.
Es=mec2{ln(reoref)+C(ref−reo)}=q2A4πεo1reo
ln(reorefeC(ref−reo))=q2A4πεomec21reo
reorefeC(ref−reo)=eq2A4πεomec21reo
refe−C.ref=reoe−C.reoe−q2A4πεomec21reo
because of the e−q2A4πεomec21reo<1 factor, and xe−Cx is monotonous increasing for x<1 for all values of C. ref<reo for r<1. Which is an acceptable result.
Given an element the constant A is determined from distribution of electrons around the positive center. The factor C....